Sodium Manganese Oxide with High Phase Purity for Performance and Cycle Stability
Our manufacturing process ensures homogeneous particle sizes in the 1-digit µm range. The patented process in the pulsation reactor delivers a homogeneous element distribution at the atomic level for optimal phase formation and higher stability during charge and discharge processes.
Property | Measured |
Particle size D10 [µm] | 1 |
Particle size D50 [µm] | 3 |
Particle size D90 [µm] | 11 |
Specific surface area [m²/g] | 1 |
Bulk density [g/cm³] | 1 - 1,4 |
Specific capacity C/10 [mAh/g] | 150 |
Data sheet | Download |
Sodium Manganese Oxide – Production and Process Description
For some time, IBU-tec has been working on the development and optimization of NMO from laboratory to industrial scale, supported by the BMBF (03XP0404A). The company's expertise in thermal process engineering is used for the production and we developed a two-stage process in which the cathode precursor compound is first produced in a pulsation reactor and then refined in a rotary kiln. This makes the process not only unique, but also comparatively energy-efficient.
Sodium-Ion Batteries
Currently, the most widely used electrochemical energy storage technology for stationary, portable and automotive applications is the lithium-ion battery (LIB). However, due to the limited availability of lithium, the high demand leads to challenges and risks. In addition, there are increasing supply risks due to (geo-)political issues. The currently intensively researched sodium-ion technology offers a future alternative to the LIB.
Cathode Materials for Sodium-Ion Batteries
Currently, in the outlook for possible commercialization of NIBs, three different types of active materials are being considered for use in cathodes: Metal oxides with layered structures, polyanionic structures, and Prussian blue analogs (PBAs).
Layered Sodium Oxides
Layered sodium oxides represent a class of cathode materials for sodium-ion batteries. The material properties can be influenced by the selection of transition metals and sodium content. In addition, a good balance of structural and electrochemical electrode properties can be achieved by combining different metals.
Advantages and Disadvantages of Sodium-Ion Batteries
Compared to lithium analogs, sodium layered oxides offer greater chemical diversity due to structural differences. While only the critical and costly metals cobalt and nickel are possible with lithium layered oxides, less critical elements such as titanium and iron can be used with sodium. In addition, the better global availability of sodium offers a significant cost advantage. Further cost savings result from the possibility of using aluminum as a current collector for both electrodes. The combination of savings opportunities offer a price advantage of approximately 16% over current LFP cells in perspective. In application, NIBs have the advantage that they can be charged and discharged at lower temperatures. This results in cost advantages, as heating and cooling systems can largely be dispensed with at module and system level. Furthermore, higher discharge rates can be realized in continuous operation. Due to the possibility of transporting Na-ion batteries in a deep-discharged state (0V), there are advantages in handling as well as transport costs, since there is no need to classify dangerous goods. In the area of cell production, a "drop-in" solution is possible, which can lead to high market penetration for EES and "low-cost" mobility solutions. Existing production facilities of LIBs can be used for NIBs, which makes production-side implementation possible quickly without immense additional costs.
One disadvantage is the currently comparatively short service life due to the strong structural changes during charging and discharging. However, the most significant disadvantage compared to LIBs is the lower energy density, due to the size and higher weight of the sodium ions. Due to the intrinsic gravimetric energy density, NIBs are particularly suitable for use in the electromobility sector for short distances, frequent charging or stationary storage.